Sorbonne-Univ./CNRS

Laboratoire de chimie de la matière condensée de Paris
Tour 44-43 / 4ème étage
Case courrier 174
4, Place Jussieu
75005 PARIS
France

Christel GERVAIS

Professeur
SMiLES

christel.gervais_stary[at]upmc.fr@-Code a retirer pour éviter le SPAM-

Christel Gervais is a chemical engineer from the Ecole Nationale Supérieure de Chimie de Paris (ENSCP) and graduated in 1996. She defended her doctoral thesis in  october 1999  in the University Pierre and Marie Curie (UPMC) now part of Sorbonne University. Her research project, performed under the supervision of Dr. F. Babonneau was focused on the characterization by solid state NMR of polymer derived ceramics (PDCs). Funded by a Marie Curie individual fellowship, she then joined the Physics Department of the University of Warwick (UK) to work on the synthesis and characterization by solid state NMR of TiO2 and mixed SiO2-TiO2 oxide nanoparticles prepared by sol-gel process, under the supervision of Pr M. E. Smith. She was hired in September 2000 at the Laboratoire de Chimie de la Matière Condensée de Paris (LCMCP) as assistant professor. In 2011, she was appointed full professor to develop a research project entitled « Spectroscopy and modeling for structural characterization of materials ».

Her research activities are centered on solid state NMR spectroscopy and deal with the characterization of a wide range of materials including nitride- or oxide-based ceramics prepared by polymeric routes, hybrid systems exhibiting an interface between an inorganic surface and (bio)organic molecules, biomaterials…. Moreover, for a few years, she combined this experimental approach with a more theoretical one based on ab-initio calculations of NMR parameters. Indeed, NMR spectra offer valuable structural information provided a careful analysis consisting for instance in assigning a chemical shift to a well defined structural site. Ab-initio calculations appear therefore a very useful tool to simulate experimental spectra and obtain data on model systems difficult to synthesize. In addition, since materials investigated by NMR are generally disordered or even amorphous, structures used as a starting point for NMR calculations can not be obtained via X-Ray diffraction : therefore she also extended her activities to  ab-initio structural modeling.

These studies are centered on the precise characterization of a matrix surface sites ((silica, HDL, MOF…) in order to study the adsorption of organic and bio-organic molecules (amino acids, peptides, drugs, pollutants). High resolution solid state NMR is a very powerful tool to investigate surfaces, adsorbed/encapsulated molecules but also interactions between both components Experiments are combined to first principles calculations to select the most relevant models.

Journal of the American Chemical Society 133 16815 (2011), Journal of Physical Chemistry C 117, 4104 (2013), Microporous and Mesoporous Materials 166, 109 (2013), Progress in Nuclear Magnetic Resonance Spectroscopy 77, 1 (2014),  Chemistry a European Journal  20, 15188 (2014), Chemistry of Materials 27, 1242 (2015) Langmuir, 32, 997 (2016) Chemistry a European Journal 22, 16531 (2016), Journal of Physical Chemistry C 121, 17339 (2017)

The Polymer Derived Ceramics (PDCs) route is based on the shaping then pyrolysis of preceramic polymers : it is an attractive means for the production of “near net shape” advanced ceramics with a large variety of organizations going from 0D to 3D such as particles and spheres, (nano)fiber or coatings for a large range of application fields. Multinuclear solid-state NMR allows a fine description of the polymer structure to better understand their rheological behavior for example their melt-spinnability. The objective is indeed to tailor the properties and processability of the systems.

Journal of Materials Chemistry 22, 17923 (2012) Journal of the American Ceramic Society, 97, 303 (2014)  Advanced Materials 26, 6548 (2014) Journal of Physical Chemistry C 119, 2783 (2015) J. Mater. Chem. A 5, 720 (2017) Chemistry a European Journal. 23, 9076 (2017), Dalton Transactions 46, 13510 (2017), Chemistry a European Journal 23, 17103  (2017), Dalton Transaction 47, 14580 (2018) Journal of the European Ceramic Society 39, 183 (2019), Royal Society Open Science  6 190690 (2019), J. Mater. Chem. A 8, 8752 (2020)

Apatites are at the crossroads of many disciplines (medicine, chemistry, paleontology, archeology, mineralogy) at the national and international level. The main inorganic component of bones is an hydroxyapatite (Ca5(PO4)3OH) substituted by carbonates. Besides the presence of carbonate groups, a large variability in chemical composition is also observed in natural samples, related to the bio-apatite formation or its post-mortem transformation. Changes in chemical composition range from cationic substitutions (eg Sr2+, Mn2+, rare earths) affecting the site of calcium, to the incorporation of anions (F, Cl) in the structural channels, and include the incorporation of hydrogen (HPO42-) and silicates (SiO44-) in the phosphate sites. The objective of this project is therefore to improve our understanding of the mechanisms controlling the chemical and isotopic composition of apatite and go further than the empirical approach often used in the interpretation of spectroscopic observations using in particular modeling and calculation of NMR parameters.

Biomaterials vol 32, 1826-1837 (2011), American Mineralogist vol 98, 1066–1069 (2013), RSC Advances vol 4,14700-14707 (2014), Physics and Chemistry of Minerals vol 41, 347-359 (2014), Acta Biomaterialia vol 10, 3952-3958, Phys Chem Minerals vol 43,  615-626 (2016), Geochimica & Cosmochimica Acta vol 219, 57-73 (2017), American Mineralogist   Vol 103,326-329, Palaeogeography, Palaeoclimatology, Palaeoecology vol 526, 80–95 (2019), ArchaeometrVol 61,1129-1143

Journal articles

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Simon Delacroix, Yann Le Godec, Cristina Coelho, Christel Gervais, Isabelle Genois, et al.. Synthesis in Molten Salts and Characterization of Li 6 B 18 (Li 2 O) x Nanoparticles. Inorganic Chemistry, American Chemical Society, 2020, 59 (20), pp.14983-14988. ⟨10.1021/acs.inorgchem.0c01694⟩. ⟨hal-02993703⟩
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Vinicius Martins, Jun Xu, Xiaoling Wang, Kuizhi Chen, Ivan Hung, et al.. Higher Magnetic Fields, Finer MOF Structural Information: 17 O Solid-State NMR at 35.2 T. Journal of the American Chemical Society, American Chemical Society, 2020, 142 (35), pp.14877-14889. ⟨10.1021/jacs.0c02810⟩. ⟨hal-02925283⟩
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https://hal.sorbonne-universite.fr/hal-02925283/file/2020_Martins_Higher_full.pdf BibTex
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Christel Gervais, Christian Bonhomme, Danielle Laurencin. Recent directions in the solid-state NMR study of synthetic and natural calcium phosphates. Solid State Nuclear Magnetic Resonance, Elsevier, 2020, 107, pp.101663. ⟨10.1016/j.ssnmr.2020.101663⟩. ⟨hal-02570411⟩
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https://hal.umontpellier.fr/hal-02570411/file/2020_Gervais_ssNMR_postprint.pdf BibTex
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Laëtitia Mayen, Nicholai Jensen, Maximilien Desbord, Danielle Laurencin, Christel Gervais, et al.. Advances in the synthesis and structure of α-canaphite: a multitool and multiscale study. CrystEngComm, Royal Society of Chemistry, 2020, 22 (18), pp.3130-3143. ⟨10.1039/d0ce00132e⟩. ⟨hal-02873559⟩
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Adi Azoulay, Jesús Barrio, Jonathan Tzadikov, Michael Volokh, Josep Albero, et al.. Synthesis of metal-free lightweight materials with sequence-encoded properties. Journal of Materials Chemistry A, Royal Society of Chemistry, 2020, 8 (17), pp.8752-8760. ⟨10.1039/D0TA03162C⟩. ⟨hal-02938216⟩
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https://hal.sorbonne-universite.fr/hal-02938216/file/2020_Azoulay_Synthesis_full.pdf BibTex
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Danielle Laurencin, Pascal Yot, Christel Gervais, Yannick Guari, Sébastien Clément, et al.. Synthesis, characterization and modeling of self-assembled porphyrin nanorods. Journal of Porphyrins and Phthalocyanines, World Scientific Publishing, 2019, 2019 Women in Porphyrin Science, 23 (11n12), pp.1346-1354. ⟨10.1142/S1088424619501451⟩. ⟨hal-02454505⟩
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Julie Aufort, Dominique Gommery, Christel Gervais, Loïc Segalen, Nathalie Labourdette, et al.. Assessing bone transformation in late Miocene and Plio‐Pleistocene deposits of Kenya and South Africa. Archaeometry, Wiley, 2019, 61 (5), pp.1129-1143. ⟨10.1111/arcm.12471⟩. ⟨hal-02097000⟩
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Lucie Ries, Eddy Petit, Thierry Michel, Cristina Coelho Diogo, Christel Gervais, et al.. Enhanced sieving from exfoliated MoS2 membranes via covalent functionalization. Nature Materials, Nature Publishing Group, 2019, 18 (10), pp.1112-1117. ⟨10.1038/s41563-019-0464-7⟩. ⟨hal-02310531⟩
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Alexandre Courac, Yann Le Godec, Carlos Renero-Lecuna, Hicham Moutaabbid, Ram Kumar, et al.. High-Pressure Melting Curve of Zintl Sodium Silicide Na4Si4 by In Situ Electrical Measurements. Inorganic Chemistry, American Chemical Society, 2019, 58 (16), pp.10822-10828. ⟨10.1021/acs.inorgchem.9b01108⟩. ⟨hal-02342905⟩
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Julie Aufort, Christel Gervais, Loïc Segalen, Nathalie Labourdette, Cristina Coelho-Diogo, et al.. Atomic scale transformation of bone in controlled aqueous alteration experiments. Palaeogeography, Palaeoclimatology, Palaeoecology, Elsevier, 2019, 526, pp.80-95. ⟨10.1016/j.palaeo.2019.03.042⟩. ⟨hal-02096955⟩
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https://hal.sorbonne-universite.fr/hal-02096955/file/Aufort%20et%20al.%20-%202019%20-%20Atomic%20scale%20transformation%20of%20bone%20in%20controlled%20.pdf BibTex
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Julie Aufort, Christel Gervais, Loïc Ségalen, Nathalie Labourdette, Cristina Coelho-Diogo, et al.. Atomic scale transformation of bone in controlled aqueous alteration experiments. Palaeogeography, Palaeoclimatology, Palaeoecology, Elsevier, 2019, 526, pp.80-95. ⟨10.1016/j.palaeo.2019.03.042⟩. ⟨hal-02991847⟩
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Zhongkan Ren, Christel Gervais, Gurpreet Singh. Preparation and structure of SiOCN fibres derived from cyclic silazane/poly-acrylic acid hybrid precursor. Royal Society Open Science, The Royal Society, 2019, 6 (10), pp.190690. ⟨10.1098/rsos.190690⟩. ⟨hal-02454315⟩
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Chrystelle Salameh, Samuel Bernard, Christel Gervais, Florence Babonneau, Alina Bruma, et al.. Chemistry of a series of aluminum-modified polysilazanes: Synthesis, pyrolysis behaviour and microstructural evolution. Journal of the European Ceramic Society, Elsevier, 2019, 39 (2-3), pp.183-194. ⟨10.1016/j.jeurceramsoc.2018.09.027⟩. ⟨hal-01944455⟩
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https://hal.umontpellier.fr/hal-01944455/file/2019_Salameh_Chemistry%20of%20a%20series_full.pdf BibTex
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Julie Aufort, Matthieu Lebon, Xavier Gallet, Loïc Segalen, Christel Gervais, et al.. Macroscopic electrostatic effects in ATR-FTIR spectra of modern and archeological bones. American Mineralogist, Mineralogical Society of America, 2018, 103 (2), pp.326-329. ⟨10.2138/am-2018-6320CCBYNCND⟩. ⟨hal-01768252⟩
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Christian Bonhomme, Xiaoling Wang, Ivan Hung, Zhehong Gan, Christel Gervais, et al.. Pushing the limits of sensitivity and resolution for natural abundance 43Ca NMR using ultra-high magnetic field (35.2 T). Chemical Communications, Royal Society of Chemistry, 2018, 54 (69), pp.9591-9594. ⟨10.1039/c8cc05193c⟩. ⟨hal-01861127⟩
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Marion Schmidt, Charlotte Durif, Emanoelle Diz Acosta, Chrystelle Salameh, Hervé Plaisantin, et al.. Molecular-Level Processing of Si-(B)-C Materials with Tailored Nano/Microstructures. Chemistry - A European Journal, Wiley-VCH Verlag, 2017, 23 (67), pp.17103 - 17117. ⟨10.1002/chem.201703674⟩. ⟨hal-01670301⟩
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Julie Aufort, Loïc Ségalen, Christel Gervais, Lorenzo Paulatto, Marc Blanchard, et al.. Site-specific equilibrium isotopic fractionation of oxygen, carbon and calcium in apatite. Geochimica et Cosmochimica Acta, Elsevier, 2017, 219, pp.57-73. ⟨10.1016/j.gca.2017.09.020⟩. ⟨hal-01598388⟩
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Antoine Viard, Diane Fonblanc, Marion Schmidt, Abhijeet Lale, Chrystelle Salameh, et al.. Molecular Chemistry and Engineering of Boron-Modified Polyorganosilazanes as New Processable and Functional SiBCN Precursors. Chemistry - A European Journal, Wiley-VCH Verlag, 2017, 23 (38), pp.9076 - 9090. ⟨10.1002/chem.201700623⟩. ⟨hal-01670294⟩
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Mirna Chaker Bechelany, Vanessa Proust, Abhijeet Lale, Philippe Miele, Sylvie Malo, et al.. Nanocomposites through the Chemistry of Single-Source Precursors: Understanding the Role of Chemistry behind the Design of Monolith-Type Nanostructured Titanium Nitride/Silicon Nitride. Chemistry - A European Journal, Wiley-VCH Verlag, 2017, 23 (4), pp.832-845. ⟨10.1002/chem.201603661⟩. ⟨hal-01518200⟩
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L. F. B. Ribeiro, Olivier Flores, P. Furtat, C. Gervais, R. Kempe, et al.. A novel PAN/silazane hybrid polymer for processing of carbon-based fibres with extraordinary oxidation resistance. Journal of Materials Chemistry A, Royal Society of Chemistry, 2017, 5 (2), pp.720-729. ⟨10.1039/c6ta09293d⟩. ⟨hal-01518198⟩
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Julia Vecchietti, Miguel A. Baltanas, Christel Gervais, Sebastian E. Collins, Ginesa Blanco, et al.. Insights on hydride formation over cerium-gallium mixed oxides: A mechanistic study for efficient H2 dissociation. Journal of Catalysis, Elsevier, 2017, 345, pp.258-269. ⟨10.1016/j.jcat.2016.11.029⟩. ⟨hal-01518199⟩
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https://hal.archives-ouvertes.fr/hal-01518199/file/vecchietti2017.pdf BibTex
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M. A. Abass, A. A. Syed, C. Gervais, G. Singh. Synthesis and electrochemical performance of a polymer-derived silicon oxycarbide/boron nitride nanotube composite. RSC Advances, Royal Society of Chemistry, 2017, 7 (35), pp.21576-21584. ⟨10.1039/C7RA01545C⟩. ⟨hal-01526779⟩
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Etienne Balan, Johanna Noireaux, Vasileios Mavromatis, Giuseppe Saldi, Valérie Montouillout, et al.. Theoretical isotopic fractionation between structural boron in carbonates and aqueous boric acid and borate ion. Geochimica et Cosmochimica Acta, Elsevier, 2017, 222, pp.117-129. ⟨10.1016/j.gca.2017.10.017⟩. ⟨hal-01628373⟩
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https://hal.sorbonne-universite.fr/hal-01628373/file/1-s2.0-S0016703717306804-main.pdf BibTex
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Christel Gervais, Cameron Jones, Christian Bonhomme, Danielle Laurencin. Insight into the local environment of magnesium and calcium in low-coordination-number organo-complexes using 25 Mg and 43 Ca solid-state NMR: a DFT study. Acta Crystallographica Section C Structural Chemistry, International Union of Crystallography, 2017, 73 (3), pp.208 - 218. ⟨10.1107/S205322961601929X⟩. ⟨hal-01480332⟩
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https://hal.sorbonne-universite.fr/hal-01480332/file/Gervais_2017_Insight_into_the.pdf BibTex
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Thomas-Xavier Métro, Christel Gervais, Anthony Martinez, Christian Bonhomme, Danielle Laurencin. Unleashing the Potential of 17 O NMR Spectroscopy Using Mechanochemistry. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2017, 56 (24), pp.6803-6807 ⟨10.1002/anie.201702251⟩. ⟨hal-01527336⟩
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https://hal.sorbonne-universite.fr/hal-01527336/file/Metro_2017_Unleashing_the.pdf BibTex
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Ruidy Nemausat, Christel Gervais, Christian Brouder, Nicolas Trcera, Amélie Bordage, et al.. Temperature dependence of X-ray absorption and nuclear magnetic resonance spectra: probing quantum vibrations of light elements in oxides. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2017, 19 (8), pp.6246 - 6256. ⟨10.1039/C6CP08393E⟩. ⟨hal-01480345⟩
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https://hal.sorbonne-universite.fr/hal-01480345/file/Nemausat_2017_Temperature.pdf BibTex
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Frederik Tielens, Nicolas Folliet, Louis Bondaz, Slavica Etemovic, Florence Babonneau, et al.. Molecular Picture of the Adsorption of Ibuprofen and Benzoic Acid on Hydrated Amorphous Silica through DFT-D Calculations Combined with Solid-State NMR Experiments. Journal of Physical Chemistry C, American Chemical Society, 2017, 121 (32), pp.17339-17347. ⟨10.1021/acs.jpcc.7b05045⟩. ⟨hal-01582612⟩
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https://hal.sorbonne-universite.fr/hal-01582612/file/Tielens_2017_Molecular_Picture.pdf BibTex
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Etienne Balan, Fabio Pietrucci, Christel Gervais, Marc Blanchard, Jacques Schott, et al.. First-principles study of boron speciation in calcite and aragonite. Geochimica et Cosmochimica Acta, Elsevier, 2016, 193, pp.119-131. ⟨10.1016/j.gca.2016.07.026⟩. ⟨hal-01371923⟩
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https://hal.sorbonne-universite.fr/hal-01371923/file/Balan_2016_First-principles.pdf BibTex
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Tanya K Todorova, Xavier Rozanska, Christel Gervais, Alexandre Legrand, Linh N Ho, et al.. Molecular Level Characterization of the Structure and Interactions in Peptide-Functionalized Metal-Organic Frameworks.. Chemistry - A European Journal, Wiley-VCH Verlag, 2016, 22 (46), pp.16531-16538. ⟨10.1002/chem.201603255⟩. ⟨hal-01546494⟩
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Oleksandr O. Kurakevych, Yann Le Godec, Wilson A. Crichton, Jérémy Guignard, Timothy A. Strobel, et al.. Synthesis of Bulk BC8 Silicon Allotrope by Direct Transformation and Reduced-Pressure Chemical Pathways. Inorganic Chemistry, American Chemical Society, 2016, 55 (17), pp.8943-8950. ⟨10.1021/acs.inorgchem.6b01443⟩. ⟨hal-01450924⟩
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Danielle Laurencin, François Ribot, Christel Gervais, Adrian Wright, Annabelle Baker, et al.. 87Sr, 119Sn, 127I Single and {1H/19F}-Double Resonance Solid-State NMR Experiments: Application to Inorganic Materials and Nanobuilding Blocks. ChemistrySelect, Wiley, 2016, 1 (15), pp.4509-4519. ⟨10.1002/slct.201600805⟩. ⟨hal-01378175⟩
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Saad Sene, Marie Pizzoccaro, Joris Vezzani, Marc Reinholdt, Philippe Gaveau, et al.. Coordination Networks Based on Boronate and Benzoxaborolate Ligands. Crystals, MDPI, 2016, Crystals, 6 (5), pp.48. ⟨10.3390/cryst6050048⟩. ⟨hal-01313402⟩
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Pierre Gras, Annabelle Baker, Christèle Combes, Christian Rey, Stéphanie Sarda, et al.. From crystalline to amorphous calcium pyrophosphates: a solid state Nuclear Magnetic Resonance perspective. Acta Biomaterialia, Elsevier, 2016, 31, pp.348-357. ⟨10.1016/j.actbio.2015.10.016⟩. ⟨hal-01221038⟩
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Thomas D. Bennett, Tanya K. Todorova, Emma F. Baxter, David G. Reid, Christel Gervais, et al.. Connecting defects and amorphization in UiO-66 and MIL-140 metal–organic frameworks: a combined experimental and computational stud. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2016, 18 (3), pp.2192-2201. ⟨10.1039/c5cp06798g⟩. ⟨hal-01270679⟩
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Julie Aufort, Loïc Ségalen, Christel Gervais, Christian Brouder, Etienne Balan. Modeling the attenuated total reflectance infrared (ATR-FTIR) spectrum of apatite. Physics and Chemistry of Minerals, Springer Verlag, 2016, 43 (9), pp.615-626. ⟨10.1007/s00269-016-0821-x⟩. ⟨hal-01331139⟩
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C. Gervais, J. Mourier, J. L. Rummer. Developing in warm water: irregular colouration and patterns of a neonate elasmobranch. Marine Biodiversity, Springer Verlag, 2016, pp 1-2. ⟨10.1007/s12526-015-0429-2⟩. ⟨hal-01270643⟩
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Frederik Tielens, Christel Gervais, Géraldine Deroy, Maguy Jaber, Lorenzo Stievano, et al.. Characterization of Phosphate Species on Hydrated Anatase TiO2 Surfaces. Langmuir, American Chemical Society, 2016, 32 (4), pp.997-1008. ⟨10.1021/acs.langmuir.5b03519⟩. ⟨hal-01269687⟩
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Ruidy Nemausat, Delphine Cabaret, Christel Gervais, Christian Brouder, Nicolas Trcera, et al.. Phonon effects on x-ray absorption and nuclear magnetic resonance spectroscopies. Physical Review B: Condensed Matter and Materials Physics, American Physical Society, 2015, 92 (14), pp.144310. ⟨10.1103/PhysRevB.92.144310⟩. ⟨hal-01224258⟩
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Imane Baroudi, Corine Sirnonnet-Jegat, Catherine Roch-Marchal, Nathalie Leclerc-Laronze, Carine Livage, et al.. Supramolecular Assembly of Gelatin and Inorganic Polyanions: Fine-Tuning the Mechanical Properties of Nanocomposites by Varying Their Composition and Microstructure. Chemistry of Materials, American Chemical Society, 2015, 27 (5), pp.1452-1464. ⟨10.1021/cm502605q⟩. ⟨hal-01275036⟩
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Lamuel David, Samuel Bernard, Christel Gervais, Philippe Miele, Gurpreet Singh. Facile Synthesis and High Rate Capability of Silicon Carbonitride/Boron Nitride Composite with a Sheet-Like Morphology. Journal of Physical Chemistry C, American Chemical Society, 2015, 119 (5), pp.2783-2791. ⟨10.1021/jp508075x⟩. ⟨hal-01275034⟩
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Saad Sene, Sylvie Bégu, Christel Gervais, Guillaume Renaudin, Adel Mesbah, et al.. Intercalation of benzoxaborolate anions in layered double hydroxides: toward hybrid formulations for benzoxaborole drugs. Chemistry of Materials, American Chemical Society, 2015, 27 (4), pp.1242-1254. ⟨10.1021/cm504181w⟩. ⟨hal-01109256⟩
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Emma F. Baxter, Thomas D. Bennett, Caroline Mellot-Draznieks, Christel Gervais, Frédéric Blanc, et al.. Combined experimental and computational NMR study of crystalline and amorphous zeolitic imidazolate frameworks. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2015, 17 (38), pp.25191-25196. ⟨10.1039/c5cp02552d⟩. ⟨hal-01275037⟩
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Dorothée Berthomieu, Christel Gervais, Guillaume Renaudin, Marc Reinholdt, Saad Sene, et al.. Coordination polymers based on alkylboronate ligands: synthesis, characterization, and computational modelling. European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2015, pp.1182-1191. ⟨10.1002/ejic.201402561⟩. ⟨hal-01175713⟩
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Nicolas Le Bail, Krystelle Lionti, Stéphane Benayoun, Sophie Pavan, Leslie Thompson, et al.. Scratch-resistant sol-gel coatings on pristine polycarbonate. New Journal of Chemistry, Royal Society of Chemistry, 2015, 39 (11), pp.8302-8310. ⟨10.1039/c5nj00426h⟩. ⟨hal-01275039⟩
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Marie-Alexandra Neouze, Martin Kronstein, Marco Litschauer, Michael Puchberger, Cristina Coelho, et al.. Exploring the Molecular Structure of Imidazolium-Silica-Based Nanoparticle Networks by Combining Solid-State NMR Spectroscopy and First-Principles Calculations. Chemistry - A European Journal, Wiley-VCH Verlag, 2014, 20 (46), pp.15188-15196. ⟨10.1002/chem.201403730⟩. ⟨hal-01275058⟩
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Monique Chan-Huot, Stephen Wimperis, Christel Gervais, Geoffrey Bodenhausen, Luminita Duma. Deuterium MAS NMR Studies of Dynamics on Multiple Timescales: Histidine and Oxalic Acid.. ChemPhysChem, Wiley-VCH Verlag, 2014, 16 (1), pp.204-215. ⟨10.1002/cphc.201402506⟩. ⟨hal-01079684⟩
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Mirna Chaker Bechelany, Vanessa Proust, Christel Gervais, Rudy Ghisleni, Samuel Bernard, et al.. In Situ Controlled Growth of Titanium Nitride in Amorphous Silicon Nitride: A General Route Toward Bulk Nitride Nanocomposites with Very High Hardness. Advanced Materials, Wiley-VCH Verlag, 2014, 26 (38), pp.6548-6553. ⟨10.1002/adma.201402356⟩. ⟨hal-01275056⟩
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Martin Depardieu, Raphaël Janot, Clément Sanchez, Ahmed Bentaleb, Rezan Demir-Cakan, et al.. Novel Au/Pd@carbon macrocellular foams as electrodes for lithium–sulfur batteries. Journal of Materials Chemistry A, Royal Society of Chemistry, 2014, 2, pp.18047-18057. ⟨10.1039/c4ta03537b⟩. ⟨hal-01089766⟩
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Haohao Yi, Etienne Balan, Christel Gervais, Loïc Ségalen, Damien Roche, et al.. Probing atomic scale transformation of fossil dental enamel using Fourier transform infrared and nuclear magnetic resonance spectroscopy: A case study from the Tugen Hills (Rift Gregory, Kenya). Acta Biomaterialia, Elsevier, 2014, 10 (9), pp.3952-3958. ⟨10.1016/j.actbio.2013.12.049⟩. ⟨hal-01093321⟩
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Danielle Laurencin, Delphine Vantelon, Valérie Briois, Christel Gervais, Antoine Coulon, et al.. Investigation of the local environment of iodate in hydroxyapatite by combination of X-ray absorption spectroscopy and DFT modeling. RSC Advances, Royal Society of Chemistry, 2014, 4, pp.14700-14707. ⟨10.1039/c3ra47691j⟩. ⟨hal-00968901⟩
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Amir H. Tavakoli, Renzo Campostrini, Christel Gervais, Florence Babonneau, Joachim Bill, et al.. Energetics and Structure of Polymer-Derived Si-(B-)O-C Glasses: Effect of the Boron Content and Pyrolysis Temperature. Journal of the American Ceramic Society, Wiley, 2014, 97 (1), pp.303-309. ⟨10.1111/jace.12658⟩. ⟨hal-01275053⟩
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Christian Bonhomme, Christel Gervais, Danielle Laurencin. Recent NMR developments applied to organic-inorganic materials. Progress in Nuclear Magnetic Resonance Spectroscopy, Elsevier, 2014, 77, pp.1-48. ⟨10.1016/j.pnmrs.2013.10.001⟩. ⟨hal-00881233⟩
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Martin Depardieu, Raphaël Janot, Clément Sanchez, Ahmed Bentaleb, Christel Gervais, et al.. Carbonaceous multiscale-cellular foams as novel electrodes for stable, efficient lithium-sulfur batteries. RSC Advances, Royal Society of Chemistry, 2014, 4, pp.23971-23976. ⟨10.1039/c4ra03110e⟩. ⟨hal-01010631⟩
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Martin Depardieu, Raphaël Janot, Clément Sanchez, Hervé Deleuze, Christel Gervais, et al.. Nano-spots induced break of the chemical inertness of boron: a new route toward reversible hydrogen storage applications. Journal of Materials Chemistry A, Royal Society of Chemistry, 2014, 2, pp.7694-7701. ⟨10.1039/c4ta00736k⟩. ⟨hal-00988199⟩
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Basma Khadro, Imane Baroudi, Anne-Marie Goncalves, Bruno Berini, Bruce Pegot, et al.. Interfacing a heteropolytungstate complex and gelatin through a coacervation process: design of bionanocomposite films as novel electrocatalysts.. Journal of Materials Chemistry A, Royal Society of Chemistry, 2014, 2 (9208-9220), pp.9208-9220. ⟨10.1039/c4ta01142b⟩. ⟨hal-01002760⟩
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Saad Sene, Dorothée Berthomieu, Bruno Donnadieu, Sébastien Richeter, Joris Vezzani, et al.. A combined experimental-computational study of benzoxaborole crystal structures. CrystEngComm, Royal Society of Chemistry, 2014, 16 (23), pp.4999-5011. ⟨10.1039/c4ce00313f⟩. ⟨hal-01016181⟩
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Haohao Yi, Etienne Balan, Christel Gervais, Loïc Segalen, Marc Blanchard, et al.. Theoretical study of the local charge compensation and spectroscopic properties of B‑type carbonate defects in apatite. Physics and Chemistry of Minerals, Springer Verlag, 2014, 41, pp.347-359. ⟨10.1007/s00269-013-0654-9⟩. ⟨hal-01010568⟩
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Elsa Alvarez, Alfonso Garcia-Marquez, Thomas Devic, Nathalie Steunou, Christian Serre, et al.. A biocompatible calcium bisphosphonate coordination polymer: towards a metal-linker synergistic therapeutic effect?. CrystEngComm, Royal Society of Chemistry, 2013, 15, pp.9899. ⟨10.1039/c3ce41346b⟩. ⟨hal-00881213⟩
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Hélène Colas, Laure Bonhomme-Coury, Cristina Coelho Diogo, Frederik Tielens, Florence Babonneau, et al.. Whewellite, CaC2O4*H2O: structural study by a combined NMR, crystallography and modelling approach. CrystEngComm, Royal Society of Chemistry, 2013, 15, pp.8840. ⟨10.1039/c3ce41201f⟩. ⟨hal-00881226⟩
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Camille Pallier, Jean-Marc Leyssale, Lionel A. Truflandier, Anh Thy Bui, Patrick Weisbecker, et al.. Structure of an Amorphous Boron Carbide Film: An Experimental and Computational Approach. Chemistry of Materials, American Chemical Society, 2013, 25 (13), pp.2618-2629. ⟨10.1021/cm400847t⟩. ⟨hal-01468408⟩
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Saad Sene, B. Bouchevreau, Charlotte Martineau, Christel Gervais, Christian Bonhomme, et al.. Structural study of calcium phosphonates: a combined synchrotron powder diffraction, solid-state NMR and first-principle calculations approach. CrystEngComm, Royal Society of Chemistry, 2013, 15, pp.8763. ⟨10.1039/c3ce40981c⟩. ⟨hal-00881221⟩
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Stuart Miller, Elsa Alvarez, Lucie Fradcourt, Thomas Devic, Stefan Wuttke, et al.. A rare example of a porous Ca-MOF for the controlled release of biologically active NO. Chemical Communications, Royal Society of Chemistry, 2013, 49, pp.7773. ⟨10.1039/C3CC41987H⟩. ⟨hal-00823982⟩
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Camille Pallier, Chollon Georges, Weisbecker Patrick, Teyssandier Francis, Gervais Christel, et al.. Structural changes of CVD Si-B-C coating under thermal annealing. Surface and Coatings Technology, Elsevier, 2013, 215, pp.178-185. ⟨10.1016/j.surfcoat.2012.07.087⟩. ⟨hal-00817348⟩
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Daniela Aiello, Nicolas Folliet, Guillaume Laurent, Flaviano Testa, Christel Gervais, et al.. Solid state NMR characterization of phenylphosphonic acid encapsulated in SBA-15 and aminopropyl-modified SBA-15. Microporous and Mesoporous Materials, Elsevier, 2013, 166 (SI), pp.109-116. ⟨10.1016/j.micromeso.2012.04.028⟩. ⟨hal-01468404⟩
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Saad Sene, Marc Reinholdt, Guillaume Renaudin, Dorothée Berthomieu, Claudio Zicovich-Wilson, et al.. Boronate Ligands in Materials: Determining Their Local Environment by Using a Combination of IR/Solid-State NMR Spectroscopies and DFT Calculations. Chemistry - A European Journal, Wiley-VCH Verlag, 2013, 19, pp.880-891. ⟨10.1002/chem.201203560⟩. ⟨hal-00784863⟩
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Nicolas Folliet, Christel Gervais, Dominique Costa, Guillaume Laurent, Florence Babonneau, et al.. A Molecular Picture of the Adsorption of Glycine in Mesoporous Silica through NMR Experiments Combined with DFT‑D Calculations. Journal of Physical Chemistry C, American Chemical Society, 2013, 117, pp.4104-4114. ⟨10.1021/jp312195a⟩. ⟨hal-00797997⟩
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Haohao Yi, Etienne Balan, Christel Gervais, Loïc Ségalen, Franck Fayon, et al.. A carbonate-fluoride defect model for carbonate-rich fluorapatite. American Mineralogist, Mineralogical Society of America, 2013, 98, pp.1066-1069. ⟨10.2138/am.2013.4445⟩. ⟨hal-00823261⟩
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M. Becuwe, P. Rouge, Christel Gervais, A. Courty, A. Dassonville-Klimpt, et al.. A new sensitive organic/inorganic hybrid material based on titanium oxide for the potentiometric detection of iron(III). Journal of Colloid and Interface Science, Elsevier, 2012, 388, pp.130-136. ⟨10.1016/j.jcis.2012.08.029⟩. ⟨hal-01468418⟩
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Christian Bonhomme, Christel Gervais, Florence Babonneau, Cristina Coelho, Frédérique Pourpoint, et al.. First-Principles Calculation of NMR Parameters Using the Gauge Including Projector Augmented Wave Method: A Chemist’s Point of View. Chemical Reviews, American Chemical Society, 2012, 112 (11), pp.5733 - 5779. ⟨10.1021/cr300108a⟩. ⟨hal-01468419⟩
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Danielle Laurencin, Christel Gervais, Holger Stork, Steffen Krämer, Dominique Massiot, et al.. 25Mg Solid-State NMR of Magnesium Phosphates: High Magnetic Field Experiments and Density Functional Theory Calculations. Journal of Physical Chemistry C, American Chemical Society, 2012, 116, pp.19984-19995. ⟨10.1021/jp307456m⟩. ⟨hal-00728158⟩
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Christian Bonhomme, Christel Gervais, Nicolas Folliet, Frédérique Pourpoint, Cristina Coelho Diogo, et al.. (87)Sr solid-state NMR as a structurally sensitive tool for the investigation of materials: antiosteoporotic pharmaceuticals and bioactive glasses.. Journal of the American Chemical Society, American Chemical Society, 2012, 134 (30), pp.12611-12628. ⟨10.1021/ja303505g⟩. ⟨hal-00726394⟩
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M. Becuwe, P. Rouge, Christel Gervais, D. Cailleu, M. Courty, et al.. Calix[4]arene-modified silica nanoparticles for the potentiometric detection of iron (III) in aqueous solution. Comptes Rendus Chimie, Elsevier Masson, 2012, 15 (4), pp.290-297. ⟨10.1016/j.crci.2011.12.008⟩. ⟨hal-01468410⟩
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Sebastien Schlienger, Johan Alauzun, Florentin Michaux, L. Vidal, Julien Parmentier, et al.. Micro-, Mesoporous Boron Nitride-Based Materials Templated from Zeolites. Chemistry of Materials, American Chemical Society, 2012, 24, pp.88. ⟨10.1021/cm201938h⟩. ⟨hal-00660595⟩
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Laura Gottardo, Samuel Bernard, Christel Gervais, Kathrin Inzenhofer, Günter Motz, et al.. Chemistry, structure and processability of boron-modified polysilazanes as tailored precursors of ceramic fibers. Journal of Materials Chemistry, Royal Society of Chemistry, 2012, 22 (16), pp.7739-7750. ⟨10.1039/c2jm15919h⟩. ⟨hal-01468500⟩
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Laura Gottardo, Samuel Bernard, Christel Gervais, Markus Weinmann, Philippe Miele. Study of the intermediate pyrolysis steps and mechanism identification of polymer-derived SiBCN ceramics. Journal of Materials Chemistry, Royal Society of Chemistry, 2012, 22 (34), pp.17923-17933. ⟨10.1039/c2jm32737f⟩. ⟨hal-01468497⟩
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Florentin Michaux, Niki Baccile, Marianne Impéror-Clerc, Luca Malfatti, Nicolas Folliet, et al.. In Situ Time-Resolved SAXS Study of the Formation of Mesostructured Organically Modified Silica through Modeling of Micelles Evolution during Surfactant-Templated Self-Assembly. Langmuir, American Chemical Society, 2012, 28 (50), pp.17477-17493. ⟨10.1021/la3038318⟩. ⟨hal-01457176⟩
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Nicolas Folliet, Claire Roiland, Sylvie Bégu, Anne Aubert, Tzonka Mineva, et al.. Investigation of the interface in silica-encapsulated liposomes by combining solid state NMR and first principles calculations.. Journal of the American Chemical Society, American Chemical Society, 2011, 133 (42), pp.16815-16827. ⟨10.1021/ja201002r⟩. ⟨hal-00692389⟩
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Marc Reinholdt, Jonas Croissant, Lidia Di Carlo, Dominique Granier, Philippe Gaveau, et al.. Synthesis and Characterization of Crystalline Structures Based on Phenylboronate Ligands Bound to Alkaline Earth Cations. Inorganic Chemistry, American Chemical Society, 2011, 50, pp.7802. ⟨10.1021/ic200961a⟩. ⟨hal-00615204⟩
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Olivier Majoulet, Johan Alauzun, Laura Gottardo, Christel Gervais, Manfred Schuster, et al.. Ordered mesoporous silicoboron carbonitride ceramics from boron-modified polysilazanes: Polymer synthesis, processing and properties. Microporous and Mesoporous Materials, Elsevier, 2011, 140, pp.40-50. ⟨10.1016/j.micromeso.2010.09.008⟩. ⟨hal-00576389⟩
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David Portehault, Sarala Devi, Patricia Beaunier, Christel Gervais, Cristina Giordano, et al.. A General Solution Route toward Metal Boride Nanocrystals. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2011, 50 (14), pp.3262-3265. ⟨10.1002/anie.201006810⟩. ⟨hal-02923117⟩
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Danielle Laurencin, Neyvis Almora-Barrios, Nora de Leeuw, Christel Gervais, Christian Bonhomme, et al.. Magnesium incorporation into hydroxyapatite. Biomaterials, Elsevier, 2011, 32 (7), pp.1826-1837. ⟨10.1016/j.biomaterials.2010.11.017⟩. ⟨hal-00556834⟩
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J. Andrieux, Umit Bilge Demirci, Julien Hannauer, Christel Gervais, Christelle Goutaudier, et al.. Spontaneous hydrolysis of sodium borohydride in harsh conditions. International Journal of Hydrogen Energy, Elsevier, 2011, 36 (1), pp.224 - 233. ⟨10.1016/j.ijhydene.2010.10.055⟩. ⟨hal-01695752⟩
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Camillo Falco, Fernando Caballero Perez, Florence Babonneau, Christel Gervais, Guillaume Laurent, et al.. Hydrothermal Carbon from Biomass: Structural Differences between Hydrothermal and Pyrolyzed Carbons via 13C Solid State NMR. Langmuir, American Chemical Society, 2011, 27 (23), pp.14460-14471. ⟨10.1021/la202361p⟩. ⟨hal-01457064⟩
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Frédérique Pourpoint, Cristina Coelho, Christel Gervais, Christian Bonhomme, Franck Fayon, et al.. High-resolution solid state NMR experiments for the characterization of calcium phosphate biomaterials and biominerals. Journal of Materials Research, Cambridge University Press (CUP), 2011, 26, pp.2355-2368. ⟨10.1557/jmr.2011.250⟩. ⟨hal-00638531⟩
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R. Paquin, P. Pelupessy, L. Dumas, C. Gervais, G. Bondenhausen. Determination of the antisymmetric part of the chemical shift anisotropy tensor via spin relaxation in nuclear magnetic resonance.. Journal of Chemical Physics, American Institute of Physics, 2010, 133 (47), pp.034506-10. ⟨10.1063/1.3445777⟩. ⟨hal-00523532⟩
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N. Brun, R. Janot, Carmen Navarro Sanchez, H. Deleuze, C. Gervais, et al.. Preparation of LiBH4@carbon miro-macrocellular foams : tuning hyrogen release through varying microporosity.. Energy & Environmental Science, Royal Society of Chemistry, 2010, 3 (35), pp.824-830. ⟨10.1039/c000858n⟩. ⟨hal-00494448⟩
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J. Li, Samuel Bernard, V. Salles, C. Gervais, P. Miele. Preparation of Polyborazylene-Derived Bulk Boron Nitride with Tunable Properties by Warm-Pressing and Pressureless Pyrolysis.. Chemistry of Materials, American Chemical Society, 2010, 22 (17), pp.2010-2019. ⟨10.1021/CM902972p⟩. ⟨hal-00466020⟩
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F. Babonneau, Niki Baccile, G. Laurent, J. Maquet, T. Azais, et al.. Solid-state nuclear magnetic resonance: A valuable tool to explore organic-inorganic interfaces in silica-based hybrid materials.. Comptes Rendus Chimie, Elsevier Masson, 2010, 13 (1-2), pp.58-68. ⟨10.1016/j.crci.2009.08.001⟩. ⟨hal-00462099⟩
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Christian Bonhomme, C. Gervais, C. Coelho, F. Pourpoint, T. Azaïs, et al.. New perspectives in the PAW/GIPAW (Gauge Including Projected Augmented Wave) approach: JP-O-Si coupling constants, antisymmetric parts of shift tensors and NQR predictions. Magnetic Resonance in Chemistry, Wiley, 2010, 48, pp.S86-S102. ⟨10.1002/mrc.2635⟩. ⟨hal-00608506⟩
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D. Caurant, O. Majérus, E. Fadel, A. Quintas, C. Gervais, et al.. Structural investigations of borosilicate glasses containing MoO3 by MAS NMR and Raman spectroscopies. Journal of Nuclear Materials, Elsevier, 2010, 396 (1), pp.94-101. ⟨10.1016/j.jnucmat.2009.10.059⟩. ⟨hal-00539978⟩
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D. Portehault, C. Giordano, C. Gervais, I. Senkovska, S. Kaskel, et al.. High-Surface-Area Nanoporous Boron Carbon Nitrides for Hydrogen Storage. Advanced Functional Materials, Wiley, 2010, 20 (42), pp.1827-1833. ⟨10.1002/adfm.201000281⟩. ⟨hal-00506087⟩
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Lorenzo Stievano, Frederik Tielens, Irene Lopes, Nicolas Folliet, Christel Gervais, et al.. Density Functional Theory Modeling and Calculation of NMR Parameters: An ab Initio Study of the Polymorphs of Bulk Glycine. Crystal Growth and Design, American Chemical Society, 2010, 10 (8), pp.3657-3667. ⟨10.1021/cg100525h⟩. ⟨hal-00604801⟩
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D. Caurant, O. Majérus, E. Fadel, A. Quintas, C. Gervais, et al.. Structural investigations of borosilicate glasses containing Mo03 by MAS NMR and Raman spectroscopies. Journal of Nuclear Materials, Elsevier, 2009, 396 (51), pp.94-101. ⟨10.1016/j.jnucmat.2009.10.059⟩. ⟨hal-00448833⟩
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Danielle Laurencin, Christel Gervais, Alan Wong, Cristina Coelho, Francesco Mauri, et al.. Implementation of High Resolution 43Ca Solid State NMR Spectroscopy: Toward the Elucidation of Calcium Sites in Biological Materials. Journal of the American Chemical Society, American Chemical Society, 2009, 131, pp.13430. ⟨10.1021/ja904553q⟩. ⟨hal-00437583⟩
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A. Pauletti, G. Moskowitz, T. Millan, C. Fernandez-Martin, C. Boissière, et al.. Aerosol-generated mesoporous silicon oxycarbide particles.. Pure and Applied Chemistry, De Gruyter, 2009, 81, pp.1449-1457. ⟨10.1351/PAC-CON-08-11-06⟩. ⟨hal-00413795⟩
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C. Gervais, L. Bonhomme-Coury, Francesco Mauri, F. Babonneau, Christian Bonhomme. GIPAW (gauge including projected augmented wave) and local dynamics in 13C and 29Si solid state NMR: the study case of silsesquioxanes (RSIO1.5)8. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2009, 11, pp.6953-6961. ⟨10.1039/b907450c⟩. ⟨hal-00411209⟩
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S. Duperrier, R. Chiriac, C. Sigala, C. Gervais, Samuel Bernard, et al.. Thermal behaviour of a series of poly(B-(methylamino) borazine) for the preparation of boron nitride fibers. Journal of the European Ceramic Society, Elsevier, 2009, 29, pp.851-855. ⟨10.1016/j.jeurceramsoc.2008.07.012⟩. ⟨hal-00411205⟩
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Sylvain Dutremez, Karim Bouchmella, Bruno Alonso, Christel Gervais, Francesco Mauri. 1H, 13C, and 15N solid-state NMR studies of imidazole- and morpholine-based model compounds possessing halogen and hydrogen bonding capabilities. Crystal Growth and Design, American Chemical Society, 2008, 8 (11), pp.3941. ⟨10.1021/cg700975v⟩. ⟨hal-00343835⟩
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Christel Gervais, Danielle Laurencin, Alan Wong, Frédérique Pourpoint, John Labram, et al.. New perspectives on calcium environments in inorganic materials containing calcium-oxygen bonds: A combined computational-experimental 43Ca NMR approach.. Chemical Physics Letters, Elsevier, 2008, 464, pp.42-48. ⟨10.1016/j.cplett.2008.09.004⟩. ⟨hal-00358177⟩
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Gilles Guerrero, Florence Brodard-Séverac, Pierre Florian, Christel Gervais, Maquet Jocelyne, et al.. High-Field 17O MAS NMR Investigation of Phosphonic Acid Monolayers on Titania. Chemistry of Materials, American Chemical Society, 2008, 20 (16), pp.5191-5196. ⟨10.1021/cm8012683⟩. ⟨hal-00327434⟩
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Frederik Tielens, Christel Gervais, Jean Francois Lambert, Francesco Mauri, Dominique Costa. Ab initio study of the hydroxylated surface of amorphous silica: A representative model. Chemistry of Materials, American Chemical Society, 2008, 20 (10), pp.3336-3344. ⟨10.1021/cm8001173⟩. ⟨hal-01361369⟩
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Dominique Costa, Asma Tougerti, Frederik Tielens, Christel Gervais, Lorenzo Stievano, et al.. DFT study of the adsorption of microsolvated glycine on a hydrophilic amorphous silica surface. Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2008, 10 (42), pp.6360-6368. ⟨10.1039/B806501B⟩. ⟨hal-00799212⟩
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A. Pauletti, S. Handjani, C. Fernandez-Martin, C. Gervais, F. Babonneau. A new example of periodic mesoporous SiCO glasses with cubic symmetry stable at 1000°C.. J. of the Ceramic Society of Japan, 2008, 116, pp.449-453. ⟨hal-00348239⟩
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D. Caurant, O. Majerus, E. Fadel, M. Lenoir, Christel Gervais, et al.. Effect of molybdenum on the structure and on the crystallization of SiO2-Na2O-CaO-B2O3 glasses.. Journal of the American Ceramic Society, Wiley, 2007, pp.774-783. ⟨hal-00326968⟩
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Gilles Guerrero, Christel Gervais, Christian Bonhomme, Cristina Coelho, Thierry Azaïs, et al.. First principles NMR calculations of phenylphosphinic acid C6H5HPO(OH): Assignments, orientation of tensors by local field experiments and effect of molecular motion. Journal of Magnetic Resonance, Elsevier, 2007, 187 (1), pp.131-140. ⟨10.1016/j.jmr.2007.03.018⟩. ⟨hal-00186742⟩
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Sylvain Duperrier, Christel Gervais, Samuel Bernard, David Cornu, Florence Babonneau, et al.. Design of a Series of Preceramic B -Tri(methylamino)borazine-Based Polymers as Fiber Precursors: Architecture, Thermal Behavior, and Melt-Spinnability †. Macromolecules, American Chemical Society, 2007, 40 (4), pp.1018-1027. ⟨10.1021/ma0623035⟩. ⟨hal-02616106⟩
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Christian Bonhomme, Cristina Coelho, Niki Baccile, Christel Gervais, Thierry Azais, et al.. Advanced solid state NMR techniques for the characterisation of sol-gel derived materials.. Accounts in Chemical Research, 2007, 40, pp.738-746. ⟨hal-00334266⟩
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Raquel Pena-Alonso, Gino Mariotto, Christel Gervais, Florence Babonneau, Gian Domenico Soraru. New insights on the high temperature nanostructure evolution of SiOC and B-doped SiOC polymer-derived glasses.. Chemistry of Materials, American Chemical Society, 2007, 19, pp.5694-5702. ⟨hal-00334158⟩
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Frédérique Pourpoint, Christel Gervais, Laure Bonhomme-Coury, Thierry Azais, Cristina Coelho, et al.. Calcium Phosphates and Hydroxyapatite: Solid State NMR Experiments and First Principles Calculations. Applied Magnetic Resonance, Springer Verlag, 2007, 32, pp.435-457. ⟨10.1007/s00723-007-0040-1⟩. ⟨hal-00343640⟩
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I. Bardez, D. Caurant, J. L. Dussossoy, P. Loiseau, C. Gervais, et al.. Development and Characterization of Rare Earth-Rich Glassy Matrices Envisaged for the Immobilization of Concentrated Nuclear Waste Solutions. Nuclear Science and Engineering, Academic Press, 2006, 153, pp.272-284. ⟨hal-00114309⟩
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S. Duperrier, Samuel Bernard, C. Gervais, D. Cornu, F. Babonneau, et al.. Controlling the chemistry, morphology and structure of boron nitride-based ceramic fibers through a comprehensive mechanistic study of the reactivity of spinnable polymers with ammonia. Journal of Materials Chemistry, Royal Society of Chemistry, 2006, 16, pp.3126-3138. ⟨10.1039/B604482D⟩. ⟨hal-00107477⟩
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I. Bardez, D. Caurant, P. Loiseau, N. Baffier, J. L. Dussossoy, et al.. Structural characterisation of rare earth rich glasses for nuclear waste immobilisation. Physics and Chemistry of Glasses, 2005, 46, pp.320-329. ⟨hal-00023497⟩
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Christel Gervais, Ray Dupree, Kevin J. Pike, Christian Bonhomme, Mickael Profeta, et al.. Combined First-Principles Computational and Experimental Multinuclear Solid-State NMR Investigation of Amino Acids.. Journal of Physical Chemistry A, American Chemical Society, 2005, 109, pp.6960-6969. ⟨10.1021/jp0513925⟩. ⟨hal-00020231⟩
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Christel Gervais, Beatriz Julian, Eloisa Cordoncillo, Purificacion Escribano, Mark E. Smith, et al.. The use of multinuclear solid state NMR for the characterization of siloxane-oxide hybrid nanocomposites. Materials Research Society Symposia Proceedings, 2005, 847, pp.EE6.2.1. ⟨hal-00077217⟩
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Christel Gervais, Mickaël Profeta, Vincent Lafond, Christian Bonhomme, Thierry Azaïs, et al.. Combined ab initio computational and experimental multinuclear solid-state magnetic resonance study of phenylphosphonic acid.. Magnetic Resonance in Chemistry, Wiley, 2004, 42, pp.445-452. ⟨10.1002/mrc.1360⟩. ⟨hal-00086010⟩
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Christel Gervais, Mickael Profeta, Florence Babonneau, Chris-J. Pickard, Francesco Mauri. Ab Initio Calculations of NMR Parameters of Highly Coordinated Oxygen Sites in Aluminosilicates.. Journal of Physical Chemistry B, American Chemical Society, 2004, 108, pp.13249-13253. ⟨10.1021/jp048462c⟩. ⟨hal-00086004⟩
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F. Sanchez, C. Gervais, A. C. Garrabrants, Radu Barna, D. S. Kosson. Leaching of inorganic contaminants from cement-based waste materials as a result of carbonation during intermittent wetting. Waste Management, Elsevier, 2002, 22 (2), p. 249-260. ⟨hal-01845784⟩
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Conference papers

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Chrystelle Salameh, Christel Gervais, Florence Babonneau, Philippe Miele. Synthesis and structural characterization of polymer derived SiAlCN ceramics. 42th International Conference and exposition on advanced ceramics and composites ICACC2018, Jan 2018, Daytona Beach, United States. ⟨hal-01826306⟩
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Antoine Viard, Christel Gervais, Florence Babonneau, Tanguy Rouxel, Yann Gueguen, et al.. Elaboration, characterization and surface modification of SilicoBoronCarboNitride ceramic hollow fibers. 6th International Congress on Ceramics (ICC-6), Aug 2016, Dresden, Germany. ⟨hal-02861532⟩
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Antoine Viard, Christel Gervais, Babonneau Florence, Sophie Cerneaux, Philippe Miele, et al.. Melt-spinnable polymer as precursor for SilicoBoroCarboNitride hollow fibers . The 6th international conference on Shaping of Advanced Ceramics, Jul 2016, Montpellier, France. ⟨hal-01687193⟩
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F. Babonneau, Claire Bonhomme, C. Gervais, Jean-Marie Nedelec, S. Gomes, et al.. Multinuclear solid state NMR characterization of substituted hydroxyapatites. 34th International Conference and Exposition on Advanced Ceramics and Composites (ICACC), Jan 2010, Daytona, United States. ⟨in2p3-00608131⟩
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Danielle Laurencin, G. Guerrero, J. Amalric, Christian Bonhomme, C. Gervais, et al.. Advanced Solid State NMR Techniques for the Investigation of the Organic-Mineral Interfaces in Biomaterials.. MRS Fall Meeting, Nov 2009, Boston, United States. pp.1236-SS08-02, ⟨10.1557/PROC-1236-SS08-02⟩. ⟨hal-00492955⟩
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Laura Gottardo, Christel Gervais, Samuel Bernard, Philippe Miele. Design and characterization of novel SiBCN preceramic polymers as potential candidates for a new generation of SiBCN ceramic fibers. 8th Pacific Rim Conference on Ceramic and Glass Technology (PACRIM8), Jun 2009, Vancouver, Canada. ⟨hal-02793670⟩
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Laura Gottardo, Samuel Bernard, Sylvain Duperrier, David Cornu, Philippe Miele, et al.. Nitride Fibers derived from Preceramic Polymers: Design, Processing and Properties. Sixth International Conference on Inorganic Materials, Sep 2008, Dresden, Germany. ⟨hal-02750815⟩
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Laura Gottardo, Samuel Bernard, Christel Gervais, A. Brioude, Corneliu Balan, et al.. Investigation of spinning curing and pyrolysis processes for the preparation of polymer derived SiBCN fibers. 8th Conference on Solid State Chemistry SSC2008, Jul 2008, Bratislava, Slovakia. ⟨hal-02750485⟩
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Daniel Caurant, Odile Majérus, Edouard Fadel, Marion Lenoir, Christel Gervais, et al.. Structural characterization of SiO2-Na2O-CaO-B2O3-MoO3 glasses. XXIst International Congress on Glass, Jul 2007, Strasbourg, France. ⟨hal-00584178⟩
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https://hal.archives-ouvertes.fr/hal-00584178/file/extended_abstract_D._Caurant_et_al._HAL_2011.pdf BibTex
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Frédérique Pourpoint, Christel Gervais, Laure Bonhomme-Coury, Francesco Mauri, Bruno Alonso, et al.. Calcium phosphates: First-principles calculations vs. solid-state NMR experiments. GERM 2007, 2007, France. pp.398-406, ⟨10.1016/j.crci.2007.09.011⟩. ⟨hal-00277151⟩
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Arnaud Quintas, Marion Lenoir, D. Caurant, Odile Majérus, Jean-Luc Dussossoy, et al.. Effet de la nature des ions alcalins et alcalino-terreux sur la structure d'un verre riche en terre. Matériaux 2006, Nov 2006, Dijon, France. ⟨hal-00172909⟩
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https://hal.archives-ouvertes.fr/hal-00172909/file/NaCa8_Materiaux2006.pdf BibTex
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Samuel Bernard, Corneliu Balan, Sylvain Duperrier, Christel Gervais, David Cornu, et al.. Spinning of Preceramic Polymers intended for the Preparation of Non-Oxide Ceramic Fibers. 3rd International Conference Shaping of Advanced Ceramics, May 2006, Limoges, France. ⟨hal-02745555⟩
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Sylvain Duperrier, Samuel Bernard, Jean-Marie Letoffe, David Cornu, Christel Gervais, et al.. Comparative study of poly[(methylamino)borazine] properties for BN fibers preparation. 107th Annual Meeting ACERS – Exposition, and Technology Fair, Apr 2005, Baltimore, United States. ⟨hal-02745392⟩
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I. Bardez, Daniel Caurant, J.-L. Dussossoy, P. Loiseau, C. Gervais, et al.. Structural Characterizations of Rare Earth-Rich Glasses for Nuclear Waste Immobilization. ATALANTE 2004 (advances for future nuclear fuel cycles), Jun 2004, Nîmes, France. ⟨hal-00177963⟩
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Book sections

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Samuel Bernard, Mirna Chaker Bechelany, Laura Gottardo, Olivier Majoulet, Ting Ouyang, et al.. Structure, Physical Properties and Industrial Application of a Particular Class of Polymer Chains: The Preceramic Polymers. Polymer Chains: Structure, Physical Properties and Industrial Uses by Régine Penzkofer et Yasue Wu (Edits); Série Chemical Engineering Methods and Technology Polymer Science and Technology, Novapublishers, 327-338, 2012. ⟨hal-02867012⟩
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Directions of work or proceedings

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Sylvain Duperrier, Rodica Chiriac, Catherine Sigala, Christel Gervais, Samuel Bernard, et al.. Shaping potentialities of aluminium nitride polymeric precursors. Preparation of thin coatings and nanostructures in soluble phase. May 2006, Limoges, France. T. Chartier, F. Rossignol (Editors), pp. 168-173, 2006, Proceedings of the 3rd International Conference on Shaping of Advanced Ceramics :Shaping 3. ⟨hal-02869773⟩
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